Pragya tested the solubility of three different substances at different temperatures and collected the data as given below (results are given in the following table, as grams of a substance dissolved in 100 grams of water to form a saturated solution). Substance dissolved Temperature in K 283 293 313 333 353 Solubility Potassium nitrate 21 32 62 106 167 Sodium chloride 36 36 36 37 37 Potassium chloride 35 35 40 46 54 Ammonium chloride 24 37 41 55 66 (a) What mass of potassium nitrate would be needed to produce a saturated solution of potassium nitrate in 50 grams of water at 313K? (b) Pragya makes a saturated solution of potassium chloride in water at 353 K and leaves the solution to cool at room temperature. What would she observe as the solution cools? Explain. (c) Find the solubility of each salt at 293 K. Which salt has the highest solubility at this temperature? (d) What is the effect of change of temperature on the solubility of a salt?
Solution:
(a) Given:
Mass of potassium nitrate required to produce a saturated solution in 100 g of water at 313 K = 62g
To find:
Mass of potassium nitrate required to produce a saturated solution in 50 g of water =?
Required amount = 62 x 50/100 = 31
Hence, 31 g of potassium nitrate is required.
(b) The solubility of potassium chloride in water is decreased when a saturated solution of potassium chloride loses heat at 353 K. Consequently, Pragya would observe crystals of potassium chloride, which would have surpassed its solubility at low temperatures.
(c) As per the given data, that is
Solubility of potassium nitrate at 293K = 32 g
Solubility of sodium chloride at 293K = 36 g
Solubility of potassium chloride at 293K = 35 g
Solubility of ammonium chloride at 293K = 37g
We can observe from this data that ammonium chloride has the highest solubility at 293K.
(d) Effect of change of temperature on the solubility of salts:
The table clearly depicts that the solubility of the salt is dependent upon the temperature and increases with an increase in temperature. With this, we can infer that when a salt arrives at its saturation point at a specific temperature, there is a propensity to dissolve more salt through an increase in the temperature of the solution.
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