What is Knocking
The objectionable metallic sound produced during the working of an internal combustion engine is known as knocking. It leads to wastage of fuel.
Factors effect Knocking.
Knocking depends upon the composition of the fuel; it falls off in the following order:
Straight chain paraffins > Branched chain paraffins > Olefins > Aromatic hydrocarbons
Knocking may also be prevented or minimised by adding small amounts of certain compounds known as anti-knock compounds, e.g. tetraethyl lead (TEL) [(C2H5)4Pb]. Such petrol is known as leaded petrol or ethyl petrol. Also Read Chemistry Formulas
Tetraethyl lead is used as a mixture of TEL (63%), ethylene bromide (26%), ethylene chloride (9%) and methylene blue (2%). About 0.5-0.6 ml of this mixture is added to 1 litre of petrol. In the cylinder of a combustion engine, TEL decomposes to produce radicals which combine with the radicals produced due to irregular combustion. As a result, the reaction chains are broken, and smooth combustion of fuel occurs. This prevents knocking.
This lead is deposited in the cylinder, which is removed by ethylene bromide to form lead bromide volatile at the ignition temperature. However, use of TEL in petrol is facing a serious problem of lead pollution. To avoid this, a new compound, cyclopentadienyl manganese carbonyl (called as AK-33-X) is used in developed countries as an anti-knocking compound.
How Knocking Occurs
In a petrol engine, the spark plug ignites the air-fuel mixture at the correct time. Ideally, the flame spreads smoothly throughout the combustion chamber.
However, if a portion of the unburnt fuel-air mixture ignites on its own due to excessive heat and pressure before the flame front reaches it, a sudden pressure wave is created. This pressure wave produces the characteristic knocking sound.
Causes of Knocking
1. Low-Octane Fuel
Fuel with a low octane rating is more likely to ignite prematurely, causing knocking.
2. High Engine Temperature
Excessive engine heat can ignite the fuel-air mixture before the spark plug fires.
3. High Compression Ratio
Very high compression increases pressure and temperature inside the cylinder, increasing the chance of knocking.
4. Incorrect Ignition Timing
If the spark occurs too early, combustion may begin before the piston reaches the correct position.
5. Carbon Deposits
Carbon deposits inside the combustion chamber can create hot spots that trigger premature ignition.
6. Lean Air-Fuel Mixture
A mixture containing too much air and too little fuel may burn at higher temperatures and contribute to knocking.
Effects of Knocking
- Reduces engine efficiency.
- Causes loss of power.
- Increases fuel consumption.
- Produces excessive engine noise.
- Can damage pistons, valves, and cylinder walls.
- Leads to overheating of engine components.
Prevention of Knocking
Use High-Octane Fuel
Higher-octane fuels resist premature ignition and reduce knocking.
Proper Engine Cooling
Maintaining an efficient cooling system prevents excessive engine temperatures.
Correct Ignition Timing
Proper adjustment of ignition timing helps ensure smooth combustion.
Regular Engine Maintenance
Removing carbon deposits and servicing the engine regularly reduces the risk of knocking.
Maintain Proper Air-Fuel Ratio
A balanced air-fuel mixture promotes efficient combustion.
Octane Number and Knocking
The octane number of a fuel indicates its resistance to knocking.
- Higher octane number → Less knocking
- Lower octane number → Greater tendency to knock
For example, premium petrol usually has a higher octane rating and performs better in high-performance engines.
Difference Between Normal Combustion and Knocking
| Feature | Normal Combustion | Knocking |
|---|---|---|
| Burning Process | Smooth and controlled | Sudden and explosive |
| Engine Sound | Quiet | Metallic knocking sound |
| Efficiency | High | Reduced |
| Engine Damage | No damage | Can cause damage |
| Fuel Consumption | Normal | Increased |
Applications of Knocking Knowledge
Understanding knocking helps:
- Design better engines.
- Improve fuel quality.
- Increase engine efficiency.
- Reduce engine wear and maintenance costs.
Key Points to Remember
- Knocking is the abnormal combustion of the air-fuel mixture in an engine.
- It produces a metallic sound known as a knock or ping.
- Low-octane fuel is a common cause of knocking.
- Knocking decreases engine efficiency and may damage engine parts.
- Using high-octane fuel and proper engine maintenance can prevent knocking.